I also have one of these, which makes makes re-work or even first time boards a breeze to solder. Have done many BGA’s with this as well.
Works like a charm. Personally, I prefer it over an oven any day.
If the pins are .1in then place your headers in a proto breadboard.
Slap on the PCB
Hold solder next to pin (Flux core 0.7mm)
Hold iron on base of Pin/PCB for a second.
Push in some solder then take away solder.
Let solder flow for a second then take away iron
Mint joint
To get a flash clean finish give it a bath in some PCB wash then an H20 rinse.