There is no explicit voltage pin in an RS232 connector standards, and as Mike says you are only getting “signal” level power from the signal pins, so you can’t really achieve what you want using as-is components.
If you look at the signal on an RS232, it’s in the order of + and - 12-15V (although modern devices rarely go to that level, I expect most to operate in the ~6v range). So it would be non-trivial to provide a few hundred milliamps from that, reliably, to allow a processor to work.